МОЛЕКУЛЯРНАЯ СТРУКТУРА 5-[(ТРИФЕНИЛФОСФОРАНИЛИДЕН)ГИДРАЗОНО]-ЭКЗО-3-АЗАТРИЦИКЛО[5.2.1.02,6]ДЕКАН-4-ОНА (330,00 руб.)

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2013.  54,  2  547.341:548.737 5-[(-)]--3--[5.2.1.02,6]-4-  -- .. 1, ..  1, ..  1, .. 1 , .. 1, ..   2 1      ,  E-mail: dokichev@anrb.ru 2   . ..  ,  -  24  2012 .    5-[()]--3[5.2.1.02,6]-4-.  27H26N3OP     P-1: a = 9,2163(9), b = 11,1102(11), c = 11,9397(12) Å, h = 74,284(2), i = = 78,532(2), t = 72,004(2).  : 5---3-[5.2.1.02,6]-4-, ,  ,  .      —             [ 1—4].        ()    — 5-[()]--3-[5.2.1.02,6]-4- 1.    1  ,   ,  -3-[5.2.1.02,6]-4- ,                    . ,   [ 5 ] ,         [ 6 ]    Ph#P#N#N#C,       N—N (1,366 Å).  .  5-[()]--3[5.2.1.02,6]-4- 1.   0,34  (2 ) 5---3-[5.2.1.02,6]-4-  200     0,52  (2 )   2      10    .  -       . : 0,36  (41 %). T 204 C.   1H (CDCl3), q, .., J, : 1,06 (, 1H, 2J 10,8, 3J 2,8, 4J 1,5, Hanti-10); 1,15, 1,40 ( ,  1H, Hendo-9, Hendo-8); 1,49 (, 1H, 2J 10,8, 3J 3,9, 4J 1,9, Hsyn-10); 1,56, 1,58 ( ,  1H, Hexo-8, Hexo-9); 2,19 (, 1H, 3J 3,9, 3J 2,8, 3J 2,3, 4J 0,7, H-1); 3,07 (, 1H, 3J 3,9, 3J 2,8, 3J 2,1, 4J 0,7, H-7); 3,21 (, 1H, 3J 6,8, 4J 1,5, 4J 0,7, H-6); 3,50 (, 1H, 3J 6,8, 4J 1,5, 3J 1,0, H-2); 6,19 (., 1H, H-3); 7,46 (, 6H, Hm, 3J 7,6, 4JHP 2,9); 7,55 (, 3H, Hp, 3J 7,6, 4J 1,5); 7,69 (, 6H, Ho, 3JHP 11,3, 3J 7,6, 4J 1,5).   13 (CDCl3, q, .., J, ): 24,91 (C9); 28,37 (C8); 31,90 (C10); 36,97 (C7); 42,20 (C1); 45,73 (C6); 57,69 (C2); 128,65 (, Cm, 3JCP 12,6); 128,96 (, Ci, 1JCP 93,1); 132,06 (, Cp, 4JCP 2,7); 133,36 (, Co, 2JCP 8,3); 150,49 (, C5, J 42,69); 170,22 (C4). ©  ..,  ..,  ..,  ..,  ..,  .., 2013    -  – -   . 405 – 407

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